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Experimental and Computational Studies of the Gas-Phase Reaction of Halon 1211 with Hydrogen

โœ Scribed by Yu, Hai; Kennedy, Eric M.; Uddin, Md. Azhar; Sullivan, Simon P.; Dlugogorski, Bogdan Z.


Book ID
125545033
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
194 KB
Volume
39
Category
Article
ISSN
0013-936X

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๐Ÿ“œ SIMILAR VOLUMES


Experimental and computational studies o
โœ Hai Yu; Eric M. Kennedy; Md. Azhar Uddin; Simon P. Sullivan; Bogdan Z. Dlugogors ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 160 KB

## Abstract Thermal pyrolysis of halon 1211 (CBrClF~2~), diluted in nitrogen, in a tubular alumina reactor, has been studied over the temperature range of 773โ€“1073 K at residence times from 0.3 to 2 s. At temperatures below 973 K, the major products were CCl~2~F~2~, CBr~2~F~2~, C~2~Cl~2~F~4~, C~2~B

Theoretical study of the gas-phase react
โœ Ikchoon Lee; Bon-Su Lee; Jae Young Choi ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 580 KB

Transition states for the two probable pathways for the gas-phase hydrolysis of hydrogen isocyanate have been determined using the MIND013 method. Activation barriers obtained showed that the one-step mechanism is preferred to the two-step mechanism involving an intermediate. It was shown that the r