Expeditious synthesis of porphyrin?cobaltacarborane conjugates
✍ Scribed by Hao, Erhong; Vicente, M. Gra�a H.
- Book ID
- 118134423
- Publisher
- Royal Society of Chemistry
- Year
- 2005
- Tongue
- English
- Weight
- 279 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1359-7345
- DOI
- 10.1039/b415649h
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📜 SIMILAR VOLUMES
a b s t r a c t meso-Tetrakis(pentafluorophenyl)porphyrin reacts with propargyl alcohol to afford porphyrins substituted with one, two, three or four prop-2-yn-1-yloxy groups in the 4-position of the meso-aryl groups. These new porphyrin derivatives react with a 6-azidoquinolone under 'click-chemist
## Abstract A simple method has been used to synthesize four porphyrin azides with cores such as N~4~, N~3~S, N~2~SO and N~2~S~2~ in 60–90 % yields by treating the corresponding aminoporphyrins with __tert__‐butyl nitrite (__t__BuONO) and azidotrimethylsilane (TMSN~3~) in THF/CH~3~CN under mild rea