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Expeditious synthesis of chiral six and seven membered nitrogen heterocycles from carbohydrate amines by N-allyl carbohydrate nitrone cycloaddition: Tuning of regioselectivity by N-substitution

✍ Scribed by Swapan Majumdar; Anup Bhattacharjya; Amarendra Patra

Book ID: 104258327
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 166 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)10287-8

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✦ Synopsis

The cycloaddition of N-allyl carbohydrate nitrones leads to enantiomerically pure six and seven membered nitrogen heterocycles and the regioselectivity of the cycloaddition can be tuned by changing the substituent on the nitrogen atom.

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