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Expedient synthesis of tetrafluorophenoxthiines and derivatives by copper(I)-catalyzed cross-coupling reaction

โœ Scribed by Yu, Chuanming; Hu, Gaobo; Zhang, Cuiling; Wu, Ran; Ye, Haiwei; Yang, Guanghui; Shi, Xiangjun


Book ID
120540999
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
783 KB
Volume
153
Category
Article
ISSN
0022-1139

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Copper(I)-catalyzed cross-coupling react
โœ Yasushi Nishihara; Kazutaka Ikegashira; Atsunori Mori; Tamejiro Hiyama ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 192 KB

A variety of unsymm~rical 1,4-biaryl-l,3-butadiyne dsrivatives are synthesized by a coppet(I)-c~alyzed cross-coupling reaction of alkynylsilanes with l-chloroalkynes in moderate to good yields. These reactions axe derived from the transmetalation of an aikynyl group from silicon to copper in a polar