Expedient Synthesis of Mono-Trimethylsilyl Hydroxylamine and Bis-Trimethylsilyl Hydroxylamine
โ Scribed by Bottaro, Jeffrey C.; Bedford, Clifford D.; Dodge, Allen
- Book ID
- 111867188
- Publisher
- Taylor and Francis Group
- Year
- 1985
- Tongue
- English
- Weight
- 115 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0039-7911
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Inhaltsu ร bersicht. Die Substitution von Halogensilanen am Lithiumderivat des N,O-Bis(trimethylsilyl)hydroxylamins findet am Sauerstoffatom statt. Durch Reaktionen im Molverha ร ltnis 1 : 1 wurden folgende O-Halogensilyl-N,Nbis(trimethylsilyl)hydroxylamine dargestellt: RSiF 2 ON (SiMe 12). Im Molv
Abstruct : Treatment of &,P(O)Cl with MesSiNI-IOSiM~ gives Pr$P(0)NHOSiMes. which is desilylated by methanol giving P&P(O)NHOH. The 0-p-nitrobenz.enesulphonyI derivative of this rearranges with KOBu' in BuYIH, an isopropyl group migrating from P to N and the phosphonamidate R'P(O)(OBu?NIIpi being fo