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Expedient N-Arylation for the Synthesis of 2-Arylamino-3-cyanopyridines Using Ionic Copper(I) Complex as a Catalyst

✍ Scribed by Zhang, Min; Ding, Yuqiang; Xiong, Biao; Wang, Ting; Yan, Fengxia; Wang, Xiaoting

Book ID: 118252027
Publisher: Japan Institute of Heterocyclic Chemistry
Year: 2012
Tongue: English
Weight: 757 KB
Volume: 85
Category: Article
ISSN: 0385-5414
DOI: 10.3987/com-12-12461

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Complexes of general formula [(NHC)Cu(μ-I) 2 Cu(NHC)] (NHC = 1-benzyl-3-butylbenzimidazolin-2-ylidene for 7; NHC = 1-benzyl-3-isopropylbenzimidazolin-2-ylidene for 8 NHC = 1-butyl-3-isopropylbenzimidazolin-2-ylidene for 9) and [(aNHC)CuI] {aNHC = 1-benzyl-3-methyl-4-phenyl-1H-1,2,3-triazol-3-ium-5-y