Expansion of Three-Membered Heterocycles to Five-Membered Cyclic Carbenes–Novel Reactions of Aziridine, Oxirane and Thiirane with CO and CS Ligands in Iron, Ruthenium, and Manganese Complexes

✍ Scribed by Dr. Mono M. Singh; Prof. Dr. Robert J. Angelici

• Book ID: 101552386
• Publisher: John Wiley and Sons
• Year: 1983
• Tongue: English
• Weight: 234 KB
• Volume: 22
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198301840

✦ Synopsis

Three-membered heterocyclic molecules YCH2CH2, where Y=NH(aziridine, 1) o r f?(oxirane, 2). react with metal-hydrid~carbonyls'~'~/ o r with carbony1 anions /293/ according