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Expanded Cubane: Synthesis of a Cage Compound with a C56 Core by Acetylenic Scaffolding and Gas-Phase Transformations into Fullerenes

✍ Scribed by Peter Manini; Walter Amrein; Volker Gramlich; François Diederich

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
145 KB
Volume
114
Category
Article
ISSN
0044-8249

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Expanded Cubane: Synthesis of a Cage Com
Expanded Cubane: Synthesis of a Cage Compound with a C56 Core by Acetylenic Scaffolding and Gas-Phase Transformations into Fullerenes
✍ Peter Manini; Walter Amrein; Volker Gramlich; François Diederich 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB

We have been interested since the early 1990s in the geometrically defined expansion of molecules by the introduction of buta-1,3-diynediyl fragments between all CÀC single bonds, thereby enhancing both the carbon atom content and the optoelectronic properties of the resulting chromophores. [1] Appl