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Exo stereoselectivity in electrophilic attack on bicyclo[4.3.1]decatetraenyl anion and in deprotonation of tricyclo[4.3.1.0]deca-2,4,7-triene

โœ Scribed by Takahashi, Kazuko; Takase, Kahei; Kagawa, Takashi


Book ID
126895203
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
858 KB
Volume
103
Category
Article
ISSN
0002-7863

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Cyclopropylallenes III: Stereoselective
โœ David E Minter; G.J Fonken; Frank T Cook ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 272 KB

In the course of an ongoing study of the chemistry of substituted cyclopropylidenes, the reactions of gem-dibromocyclopropanes with methyllithium have been used recently in our laboratories to generate a variety of highly strained cyclic allenes.' We report here the syntheses and thermal rearrangeme