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exo-Selective Asymmetric Diels–Alder Reaction Catalyzed by Diamine Salts as Organocatalysts

✍ Scribed by Taichi Kano; Youhei Tanaka; Keiji Maruoka

Book ID
112005310
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
130 KB
Volume
2
Category
Article
ISSN
1861-4728

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Diels-Alder reacfions ofsilyloxydiene 1 derivedfrom 1 -acetylcyclohexene with imincs 26 and 2c occur with high exe selectivity depending upon experimental cundirinns: exo cycloadducts 3h-c are e\_zciusively formed under kinetic control using rerf-butyIdimethyt.rilyllriflate us catalyst. In [he prese