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Exo-endo steric impediment in norbornene. Specification of the transition state for the reaction of singlet oxygen with 2-methylnorborn-2-ene and 2-methylenenorbornane

✍ Scribed by Jefford, C. W.; Laffer, M. H.; Boschung, A. F.

Book ID
126861377
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
262 KB
Volume
94
Category
Article
ISSN
0002-7863

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Reaction of Singlet Oxygen with 2-Methyl
Reaction of Singlet Oxygen with 2-Methylnorborn-2-ene, 2-Methylidenenorbornane, and their 7,7-Dimethyl Derivatives. The transition state geometry for hydroperoxidation
✍ Charles W. Jefford; André F. Boschung 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 963 KB

## Abstract The dye‐sensitized photo‐oxygenation of 2‐methylnorbonr‐2‐ene (**3**), 2‐methylidene‐norbornane (**4**) and their 7,7‐dimethyl derivatives (**5** and **6**) has been studied. In all cases allylically rearranged hydroperoxides were formed, except that **4** also gave a little norbornanon