Existence of long-lived radicals in the γ-radiation induced polymerization of ethylene
✍ Scribed by Machi, Sueo ;Hagiwara, Miyuki ;Gotoda, Masao ;Kagiya, Tsutomu
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1965
- Tongue
- English
- Weight
- 195 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0449-2951
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## Abstract Studies of the rates of γ‐radiation‐initiated polymerization of ethylene in the gas phase at 22°C., 40–70 atm. and 380,000 r/hr. have shown that the rate expressions show a good correlation with the relations expected from kinetic considerations if the density is used to express the eth
The polymerization of N-methylmethacrylamide (NMMAm) with azo-bis-isobutyronitrile (AIBN) was kinetically investigated in cyclohexane which has a small affinity for NMMAm monomer. The polymerization proceeded heterogeneously. The polymerization rate (Rp) was expressed by the following equation: The