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Excluded-volume effects in the diffusion of hard spheres

✍ Scribed by Bruna, Maria; Chapman, S. Jonathan

Book ID
115441645
Publisher
The American Physical Society
Year
2012
Tongue
English
Weight
425 KB
Volume
85
Category
Article
ISSN
1063-651X

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The selfdiffusion coefficient (0) of a hard sphere of variable sire and mass, moving in a solvent of hard spheres of fved size and mass, is calculated in a version of the ring approximation (RA). It is found that (a) the ring contribution to D vanishes for particles smaller or less massive than the