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Excluded volume effect and non-newtonian viscosity of dilute solutions of flexible macromolecules

โœ Scribed by Okano, Koji ;Wada, Eiichi

Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
55 KB
Volume
15
Category
Article
ISSN
0449-2994

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โœ Claude Wolff ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 621 KB

The shear-thickening of di'lute solutions of flexible macromolecules of high molecular weight is explained theoretically assuming the existence of one-to-one reversible.concentratian and shear rate dependent associations between the macromolecules. The theoretical curves obtained are in fairly good

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Ab~racl--Kinetic effects of excluded volume and selective adsorption in macromolecule solutions have been studied for an arbitrary position of reacting groups along the chain. It has been shown that the reactivities of similar functional groups can depend upon their location along the chain and also