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Excluded Volume: A Historical Enigma of the van der Waals Equation of State †

✍ Scribed by Rusanov, Anatoly I.

Book ID
120493504
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
247 KB
Volume
55
Category
Article
ISSN
0021-9568

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The Van Der Waals equation of state has been modified in order to improve its accuracy. The introduction of a temperature dependence of the attraction term allows reproducing accurately purecompound vapour pressures. The modification of the mixing rules, with the infinite-pressure excess-freeenergy

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A cubic equation of the van der Waals type 1s presented wtth the cntlcal compress~lxhty factor taken as substance dependent Input requrrements are Pltzer's acentnc factor and the crItIca temperature and pressure Parameter b IS treated as Independent of temperature, and the temperature dependence of