Excitons in polymerized diacetylenes

✍ Scribed by Michael R. Philpott

• Publisher: Elsevier Science
• Year: 1977
• Tongue: English
• Weight: 443 KB
• Volume: 50
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(77)80671-4

✦ Synopsis

A simple cxtiton theory for the cxcrted clcctronie States of poly-Z,4-hcxadiyn-1,6-dlo1 his@-toluenc sulpfronnte) is &w_ribeti. ~~~f]~IIr~ti~n itttcrartion between bond cxci~oos, dtargc trdrtsfcr c&ton\ dnd two-cpcttan States is inciudcd in the theory. The K = 0 levels are dcscrlbed dnd their parentage traced to Icvcl~ in two model compounds, virlyI acetylene artd cyclododccatricnctriync.

1 hc 2 eV trahtmn Of the polymer is predicted to bc 'i coltectivc state of the bond and charge twnsfer cxciton\ wit11 no two-exciton cotItpon~nt.

The lowest tnplet state IS prcdzcted to Ire below the first singlet and to also have extenswe charge transfer charxtcr.