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Excitonic properties of the polar faces of bulk ZnO after wet etching

✍ Scribed by J. Fryar; E. McGlynn; M.O. Henry; A.A. Cafolla; C.J. Hanson


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
391 KB
Volume
340-342
Category
Article
ISSN
0921-4526

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✦ Synopsis


We examine the effects of acid etchants on the two polar faces of bulk ZnO using photoluminescence and reflectance spectroscopy, as well as changes in surface topography using atomic-force microscopy. Although the (0 0 0 À1) surface exhibits intense bound-exciton emission and strong free-exciton resonances, these are quenched for the (0 0 0 1) surface. We attribute this to the polish quality of each polar face, and compare the effects of each etchant solution on surface topography and excitonic features.