The temperature dependence of the fluorescence spectra ofqegregates in napkthalene-perdcuteronaphthalcnc mixed crysti has been investigated between 1.4 and 70 K and for concentrations up to 50% naphthalene. It is shcwn that the most abundant traps -the monomer guest molecules -transfer energy like
Excitonic energy transfer in mixed-stack charge transfer crystals
✍ Scribed by Bolesław Kozankiewicz
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 272 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1616-301X
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✦ Synopsis
Excitonic energy transfer in mixed-stack charge transfer (CT) crystals doped with anthracene was studied within the temperature range 5-300 K using optical, spectroscopic and kinetic techniques. Excitons were found to be self-trapped at low temperature and mobile at higher temperatures, with the activation energy of mobility being dependent on their CT character. A 1D hopping model describes the motion of triplet excitons, whereas a 3D model fits the migration of singlet excitons.
📜 SIMILAR VOLUMES
The reflection spectrum of the fust singlet charge transfer transition of anthracene-PMDA (pyromeflitic dianhydride) crystal has been obt.dned at temperatures close to 2 K. The spectrum is polarized along the stack axis and consists of a series of vrbronic bands, approximately 500 cm-l wide, with im