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Excited states of poly(vinyl cinnamate) studied by low-energy electron loss spectroscopy and inmdo/s computation

✍ Scribed by S. Oikawa; M. Tsuda; N. Ueno; K. Sugita


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
486 KB
Volume
74
Category
Article
ISSN
0009-2614

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✦ Synopsis


The low-energy electron loss spectrum of poiy(vmy1 cinnamate) film was measured as a function of impact energy. EKcited states of the polymer were also investigated by an INDO/S MO calculaatlon using cinnanuc acid as a model. The c&ulated results agree well with the evperunental results both for trIplet and smglet excitatmns, indicatmg that the observed excttations (2 8,45,5 8 and 7 eV) are locabzed III the pendant group of the polymer.