Excited states of mixed ligand complexes of ruthenium (II) with 2-(2-Pyridyl) quinoline and 2,2-biquinoline
β Scribed by David M. Klassen
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 331 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Rccewcd 30 Augusl 1983. hlacd-hgand complcwr 01 ruthcnum(ll) containmg 7--(?'-pyrldyl)qulnollnc (pq) .~nd 2,2'-b,q",n"llne (b1q) IWU bcL!n synrhcslzcd and sludlcd Room-lcmpcrahuc rbsorptmn spectra dnd ICW-~cmpcr~~urc cnussmn spectra and l~tcrmtcr Itrvc been measured dnd mrhcalc thdl lhc lowcsl ewkd chargelransfcr slates are lowlucd on cllhcr !hc pq or blq hg~nd
π SIMILAR VOLUMES
The two new ligands N- [(2-pyridyl)methyl]-2,2Π-dipyridylamine (L1) and N-[bis(2-pyridyl)methyl]-2-pyridylamine (L2) have been synthesized and the copper(II) complexes [Cu(L1) 2 (CH 3 OH) 2 ](ClO 4 ) 2 , [Cu(L1) 2 (H 2 O) 2 ](ClO 4 ) 2 , [Cu 3 -(L1) 2 (DMF) 2 Cl 6 ], [Cu(L1)Cl 2 ] n , [Cu(L2)(Cl)(Cl
## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^β^ = violurate anion and bipy = 2,2β²bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^β^ analogue. In the former, the electronic band at 4
## Abstract Excitation of Ru(bipy)~3~^2+^ ion by visible radiation of wavelength Ξ» = 436 nm in aqueous medium in presence of inorganic peroxides, peroxomonosulfate (PMS), peroxodisulfate (PDS), and peroxodiphosphate (PDP) was found to generate Ru(bipy)~3~^3+^. The kinetics of this photochemical oxi