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Excited-state proton-transfer kinetics: a theoretical model

โœ Scribed by Arnaut, Luis G.; Formosinho, Sebastiao J.


Book ID
121255442
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
852 KB
Volume
92
Category
Article
ISSN
0022-3654

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๐Ÿ“œ SIMILAR VOLUMES


Excited-state proton transfer kinetics o
โœ Anunay Samanta; Nitin Chattopadhyay; Debnarayan Nath; Tapanendu Kundu; Mihir Cho ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 371 KB
Excited state proton transfer kinetics o
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Fluorimetric titrations of 4-hydroxydiphenyl ether and its anion give stretched sigmoid curves with two inflection points. This reveals that the rates of excited state proton exchange are comparable to the rates of deactivation of the conjugate pair. These curves are analyzed using the lifetimes of

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## 3aminoacridme (I) has been used to extend the quantitation of acited-state proton-transfer kinetics in concentrated acid media to ==13 hl sulfuric acid. The hydration requirement of tire reaction and the reasons for its not attaining equilibrium witbin the lifetime of the excited state are disc