Excited-state proton-transfer kinetics: a theoretical model
โ Scribed by Arnaut, Luis G.; Formosinho, Sebastiao J.
- Book ID
- 121255442
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 852 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Fluorimetric titrations of 4-hydroxydiphenyl ether and its anion give stretched sigmoid curves with two inflection points. This reveals that the rates of excited state proton exchange are comparable to the rates of deactivation of the conjugate pair. These curves are analyzed using the lifetimes of
## 3aminoacridme (I) has been used to extend the quantitation of acited-state proton-transfer kinetics in concentrated acid media to ==13 hl sulfuric acid. The hydration requirement of tire reaction and the reasons for its not attaining equilibrium witbin the lifetime of the excited state are disc