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Excited-state properties of [(OC)5W(L)W(CO)5][L = 4,4?-bipyridyl (4,4?-bipy) or pyrazine] and [(OC)5W(4,4?-bipy)]

โœ Scribed by George, Michael W.; Johnson, Frank P. A.; Turner, James J.; Westwell, Jeremy R.


Book ID
121390108
Publisher
The Royal Society of Chemistry
Year
1995
Tongue
English
Weight
1019 KB
Volume
17
Category
Article
ISSN
1472-7773

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The reactions of [N 3 P 3 (dobp) 2 Cl 2 ] and [N 3 P 3 (dobp)Cl 4 ] with revealed that the complexation of the N atom of one 4oxypyridine ligand by the W(CO) 5 fragment has a a mixture of HOC 5 H 4 N-4 and K 2 CO 3 in acetone give the cyclotriphosphazenes [N 3 P 3 (dobp) 2 (OC 5 H 4 N-4) 2 ] and [N