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Excited State Intramolecular Proton Transfer in Schiff Bases. Decay of the Locally Excited Enol State Observed by Femtosecond Resolved Fluorescence

✍ Scribed by Rodríguez-Córdoba, William; Zugazagoitia, Jimena S.; Collado-Fregoso, Elisa; Peon, Jorge


Book ID
118228949
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
169 KB
Volume
111
Category
Article
ISSN
1089-5639

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The keto-type reaction product of intramolecular proton transfer in the excited state of 2-(2'-hydroxy-5'methylphenyl)benzotriazole is investigated by femtosecond experiments in a wide spectral range. Keto-type molecules produced on a 100 fs time scale show an emission band between 600 and 800 nm th