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Excited-State Energy-Transfer Dynamics of Self-Assembled Imine-Linked Porphyrin Dyads

✍ Scribed by Sazanovich, Igor V.; Balakumar, Arumugham; Muthukumaran, Kannan; Hindin, Eve; Kirmaier, Christine; Diers, James R.; Lindsey, Jonathan S.; Bocian, David F.; Holten, Dewey


Book ID
120343528
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
252 KB
Volume
42
Category
Article
ISSN
0020-1669

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Dyads of a N-confused porphyrin (NCP) moiety covalently linked to a porphyrin free-base (H 2 P) or a zinc(II) porphyrinate (ZnP) moiety via a flexible alkyl chain of variable length have been synthesized. Photoluminescence study demonstrated an efficient excitation energy transfer from H 2 P/ZnP moi