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Excited-State Dynamics of Tetraphenylethylene: Ultrafast Stokes Shift, Isomerization, and Charge Separation

✍ Scribed by Zijlstra, Robert W. J.; van Duijnen, Piet Th.; Feringa, Ben L.; Steffen, Thomas; Duppen, Koos; Wiersma, Douwe A.


Book ID
120213013
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
309 KB
Volume
101
Category
Article
ISSN
1089-5639

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The process of intramolecular charge separation was studied in three nearly identical donor-bridge-acceptor compounds (1-3) under jet-cooled conditions. Each consists of a vinylcyanonaphthalene group as a powerful electron acceptor and an anilino derivative as an electron donor, separated by a rigid