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Excited-State Double-Proton Transfer in the 7-Azaindole Dimer in the Gas Phase. 2. Cooperative Nature of Double-Proton Transfer Revealed by H/D Kinetic Isotopic Effects

✍ Scribed by Sakota, Kenji; Sekiya, Hiroshi


Book ID
127200635
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
116 KB
Volume
109
Category
Article
ISSN
1089-5639

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I-or the 7azaindole dimer (ND) in 3-methylpentane. the metastable ground-state dimeric tautomer generated through an exIted\_state double proton transfer and its subsequent reIaxation was detected by transient absorption and twostep laser excitation fluorescence spectroscopies. The second laser exci