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Excited singlet states of molybdenum chloride clusters

✍ Scribed by U. Strauss; N. Perchenek; W.W. Rühle; H.J. Queisser; A. Simon

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
313 KB
Volume
202
Category
Article
ISSN
0009-2614

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✦ Synopsis

Excited singlet states of [Mo&l,~]'-cluster anions, as previously predicted but undiscovered, are detected in single crystals of [N(C,H,)&Mo&I,, by means of photoluminescence measurements with time resolution in the picosecond regime. The intensity of one of the transitions shows an unexpected dependence upon beam incidence angle relative to the crystallographic axes.

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