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Excited molecules and clusters in solid media. Hydrogen and tetrahydrogen in ionic crystals

✍ Scribed by C.A. Nicolaides; P. Valtazanos; N.C. Bacalis

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
392 KB
Volume
151
Category
Article
ISSN
0009-2614

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✦ Synopsis

We present accurate results from full CI calculations on ground and excited states ofHL and (H?).' embedded in AgF and RbI solids. It is found that the effect of these crystals on the spectra and on the energy surface characteristics is considerable. This finding suggests that, with a suitable selection of solid medta, it may become possible to manipulate substantially the electromc spectroscopy and the energy storage and dissipation of certain classes of molecules and clusters.

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