Excitation phenomena and line intensities in high-resolution NMR powder spectra of half-integer quadrupolar nuclei
β Scribed by Samoson, A.; Lippmaa, E.
- Book ID
- 124162468
- Publisher
- The American Physical Society
- Year
- 1983
- Tongue
- English
- Weight
- 260 KB
- Volume
- 28
- Category
- Article
- ISSN
- 1098-0121
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π SIMILAR VOLUMES
Two signal enhancement schemes capable of providing large signal-to-noise gains in static and magic-angle spinning NMR spectra of the central transition of half-integer quadrupolar nuclei are presented. Amplitude-modulated doublefrequency sweeps (AM-DFS) and rotor-assisted population transfer (RAPT)
Three population transfer techniques for improving the sensitivity of the central transition of NMR spectra from half-integer quadrupolar nuclei in the solid state are described. Two of the methods attempt to invert the populations of energy levels associated with the satellite transitions either by