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Excitation and deactivation of molecular rotation in atom-molecule collisions

โœ Scribed by A. V. Ivanov; B. V. Kuksenko; S. A. Losev

Publisher
SP MAIK Nauka/Interperiodica
Year
1974
Tongue
English
Weight
525 KB
Volume
12
Category
Article
ISSN
0021-8944

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๐Ÿ“œ SIMILAR VOLUMES

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Cross sections fOi rotational excitation'are calculated classically for coilisions ofH with CO and of He with HCN. The H+-CO cross sections are in good agreement with quantum results but the He+HCN results are not. Tix failure of the classical method, when applied to He+HCN, is attributed to the neg

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If the collisional ionization is chiefly due to energy transfer from the polar-molcculc rotation to an electron in a high Rydberg state of the atom, then theory predicts that the cross section averaged over a thermal distribution of rotational states should show step-like structure as a function of

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The results of classical trajectory calculations for rigid rotator p-Ha-p-Ha collisions are presented. Several trajectory methodologies are compared\_ Over the energy range for which quanta1 results are available classical-quanta1 comparisons are poor.