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Exciplex formation upon recombination of radiation-generated radical ion pairs in nonpolar solutions

✍ Scribed by A. R. Melnikov,E. V. Kalneus,V. V. Korolev,I. G. Dranov…


Book ID
121613746
Publisher
SP MAIK Nauka/Interperiodica
Year
2013
Tongue
English
Weight
181 KB
Volume
452
Category
Article
ISSN
0012-5016

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Picosecond laser photolysis of 9, IO-dibromoanthracene (DBA) in acetonitrile-triethylamine (TEA) reveals no absorption due to an exciplex (between the lowest excited singlet state of DBA and the ground-state TEA), probably owing to its rapid decomposition into the radical anion (DBA-' ) of DBA and t