✦ LIBER ✦

Excimer formation of pyrene as a probe to investigate the recombination of geminate pairs: effect of multicomponent recombination on Stern-Volmer plot

✍ Scribed by Masaharu Okazaki; Yutaka Tai; Keichi Nunome; Kazumi Toriyama

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 446 KB
Volume: 171
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)85259-f

No coin nor oath required. For personal study only.

✦ Synopsis

Quenching of excimer and monomer fluorescences induced by X-ray and W-light as well as that of ODESR amplitude was observed with freon 113 as the quencher. The Stem-Volmer plots of these results show a bend at low quencher concentrations. Analysis of these plots give some precise information on the kinetic processes of the delayed geminate pairs.

📜 SIMILAR VOLUMES

Excimer formation of pyrene as a probe t

Excimer formation of pyrene as a probe to investigate the recombination of geminate pairs: ODESR and fluorescence study of dilute pyrene in squalane

✍ Masaharu Okazaki; Yutaka Tai; Ryoichi Nakagaki; Keichi Nunome; Kazumi Toriyama 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 504 KB

It is shown that the monomer fluorescence and the excimer fluorescence from a dilute pyrene solution in squalane at room temperature are mainly from "delayed" geminate pairs (Py-, S+) and (Py-, Py+ ), respectively, from the ODESR spectra observed at the monomer and the excimer fluorescence. The reco