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Excimer formation and trapping processes in molecular crystals

✍ Scribed by L.A. Dissado; S.H. Walmsley


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
365 KB
Volume
87
Category
Article
ISSN
0009-2614

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✦ Synopsis


Rcccwcd 18 Deccmbcr 1981

The theory oiewuner formslion m molecule crystals IS dlscusscd. both locAked rmd cwton-ld~ e~cimrrs being conudered. Dlifercnt mcchxusms oielccrromc and \lbratlonal relaxtrion are mtroduced and compared. Reiaence is made IO typical systems such 3s pyrene and 9cywoxnrhraccne.


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Exciton traps in molecular crystals at low temperature are discussed for three types: chemical traps formed by fareign molecules, physical traps formed by structural disturbance of the host or pure crystal and self-traps. Self-traps are redefΓ―ned in terms of intra-and Γ―ntermolecular processes which