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Excimer fluorescence determination of solid-liquid interfacial pyrene-labeled poly(acrylic acid) conformations

✍ Scribed by Chandar, Prem.; Somasundaran, P.; Turro, Nicholas J.; Waterman, Kenneth C.


Book ID
126994659
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
360 KB
Volume
3
Category
Article
ISSN
0743-7463

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By means of time-resolved total internal reflection (TIR) fluorescence measurements, rise and decay profiles of the pyrene excimer fluorescence were examined in toluene containing 3.3x 10e4 mol dm-" of poly(methy1 methacrylate) (PMMA, MW= 120000). In addition to a reduction of the fluorescence inten