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Excimer dynamics of poly(n-vinylcarbazole) films revealed by time-correlated single photon counting measurements

โœ Scribed by Akira Itaya; Hisashi Sakai; Hiroshi Masuhara


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
494 KB
Volume
138
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Precise rise and decay curves of excimer emissions of poly( N-vinylcarbazole) films in the picosecond time region have been measured by using a time-correlated single photon counting technique. The partial overlap excimer fluorescence was observed immediately after excitation, while the sandwich excimer fluorescence showed delayed formation processes. These results were quite different from those reported before, discussed in terms of high intensity excitation and photo-oxidation effects.


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Combining the measurements of the picosecond transient absorption spectra and the transient dichroism sensitive to the charge shift reaction processes, photoinduced charge separation (CS), recombination (CR) and hole transfer (HT) processes in poly(N-vinylcarbazole) solid films doped with electron a