Exchange of azine ligands in fac-Re(CO)3(4-cyanopyridine)2Cl and fac-Re(CO)3(quinoline)2Cl
β Scribed by G. Ferraudi; Neyde Murakami Iha; G. Ruiz; E. Wolcan; M.E. Feliz
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 388 KB
- Volume
- 221
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract __We have synthesized and fully characterized four new complexes comprising the__ fac__β[Re(CO)~3~]__^__+__^ __moiety and the ligands NH~3~, Lβproline (Pro), or__ N,N__βdimethylglycine (dmGly). The reaction of [Re(H~2~O)~3~(CO)~3~]__^__+__^ __with the two amino acids gives trinuclear co
KU X-ray photoelectron (ESCA) ,qrectra of the Co 2p levels have been obtained in fnrns-and ci%[Co(NHa)&a ] Cl isomers\_ It is observed that these compounds slowly decompose under X-ray irradiation. A procedure is employed to record real spectra for both the trans and cis isomers without any sighican