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Exchange Energy on Alkali Diatomic Molecules: Period Effects

โœ Scribed by C.E. Fellows; R.F. Gutterres; P.S. Rocha; C.E. Leal

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
135 KB
Volume
185
Category
Article
ISSN
0022-2852

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โœฆ Synopsis

The exchange energy in the long-range near-dissociation region is analyzed for the ground electronic states of homoand heteronuclear alkali diatomic molecules. The analysis is based on the use of the functional form Ae 0ar to represent this exchange term. A period effect is observed in the values of both parameters and the exponent parameter a appears to approach an asymptotic limit for the heavier molecules. The results obtained in this study also suggest that some care must be taken in using even this function to represent the exchange energy.

๐Ÿ“œ SIMILAR VOLUMES

On the vibrational energy accumulation i
On the vibrational energy accumulation in matrix-isolated diatomic molecules
โœ G. Zumofen ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 413 KB

## Recent experimental tnvesttgatrons of the popufar~on evofutron of the vibrational states of CO dduted in Ar indtcatc Ihat the rates of tbc reactions CO( 1) + CO(u) -CO(O) + CO(u + 1) \* ti Increase with u for u = l-3, and that they are approxrmatcly constant for u = 3-5. This surpnsmg and unexp