Exchange Currents at Liquid Electrodes
β Scribed by BASS, L.
- Book ID
- 109631702
- Publisher
- Nature Publishing Group
- Year
- 1963
- Tongue
- English
- Weight
- 267 KB
- Volume
- 200
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/200667b0
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π SIMILAR VOLUMES
The standard exchange cd for IrCl, \*--) IrCI,\*-in 0.5 N HCl was determined at an anthracene electrode to be iOn = 1.5 -7 x lo-\* A/cm\*. From the rate constant of the chemical exchange reaction, a value iOn = 10-4A/cmP is predicted for the same system from the Franck-Condon theory restricted elect
Standard exchange current densities (&,,) of various aqueous redox systems at platinum electrodes have been calculated from literature exchange current densities and their measured variation with concentration or electrode potential. Values for the systems Ce(IV)/Ce(III), Mn(IV)/ Mn(III), Mn(III)/Mn