Exchange coupled linear heterotrinuclear complexes, FEIIIMIIFEIII and MNIII MII MNIII (M = ZN, CU, NI, FE, CO, MN). Electrochemistry, magnetic properties and structures.

Metal–Organic Perovskites: Synthesis, St

Metal–Organic Perovskites: Synthesis, Structures, and Magnetic Properties of [C(NH2)3][MII(HCOO)3] (M=Mn, Fe, Co, Ni, Cu, and Zn; C(NH2)3= Guanidinium)

✍ Ke-Li Hu; Mohamedally Kurmoo; Zheming Wang; Song Gao 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 615 KB

## Abstract We report the synthesis, crystal structures, and spectral, thermal, and magnetic properties of a family of metal–organic perovskite ABX~3~, [C(NH~2~)~3~][M^II^(HCOO)~3~], in which A=C(NH~2~)~3~ is guanidinium, B=M is a divalent metal ion (Mn, Fe, Co, Ni, Cu, or Zn), and X is the formate