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Excess thermodynamic properties of {xc-C6H10O+(1−x)(n-C7H16orc-C6H12)} atT=298.15 K

✍ Scribed by Koji Nishikawa; Katsutoshi Tamura; Sachio Murakami

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
229 KB
Volume
30
Category
Article
ISSN
0021-9614

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✦ Synopsis

Densities of the mixtures 7 16 6 12

were also measured at temperatures 298.15 K and 308.15 K and their excess thermal expansive coefficients estimated. Molecular shapes of second components have significant effect on the excess properties. The thermal properties were similar to each other but volumetric properties were considerably different. Non-polar components break the dipolar interaction of ketones, but ketone molecules instantaneously reorient to more stable dipolar orientation. As a result, non-randomness was observed.

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