Excess molar enthalpies of methanol–cyclohexane and methanol–benzene from 454.2 to 523.0 K and up to 4 MPa
✍ Scribed by Massucci, Mario; Wormald, Christopher J.
- Book ID
- 115459651
- Publisher
- Royal Society of Chemistry
- Year
- 1993
- Tongue
- English
- Weight
- 611 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0956-5000
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📜 SIMILAR VOLUMES
A new differential flow mixing calorimeter for operation at high temperature and pressures is reported. The calorimeter has been used to make measurements of excess enthalpies H E m for {xH2O + (1-x)CH3OH} over the temperature range T=423 K to T=523 K at pressures up to 20 MPa. The measurements are
cyclohexane q tetrachloromethane g and benzene q tetrachloromethane g at standard atmospheric pressure over the temperature range 353.2 K to 423.2 K. The non-ideality of the cyclohexane, benzene, and tetrachloromethane was fitted using the Kihara potential. Cross-Ž . Ž . 1 r 2 terms were calculated