𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Examination of P−OR Bridging Bond Orders in Phosphate Monoesters using 18 O Isotope Shifts in 31 P NMR

✍ Scribed by Sorensen-Stowell, Kerensa; Hengge, Alvan C.

Book ID
120474084
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
113 KB
Volume
70
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Extremely large one-bond 31P13C and two-
Extremely large one-bond 31P13C and two-bond 31P18O isotope shifts in [(H3C)2CH]3SiOCP, a new representative of λ3-phosphaalkynes, and isotope shifts of several derivatives and some λ3-phosphaalkenes
✍ Gernot Heckmann; Gerd Becker; Hans Kraft 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB

The structure of the heteroatom-substituted 3 -phosphaalkyne [(H 3 C 2 CH] 3 Si-O-C P (1) was derived from the 31 P, 13 C, 29 Si and 17 O NMR spectra. The phosphorus atom of the non-isotope-enriched compound exhibits an extremely negative 31 P 13 C one-bond and 31 P 18 O two-bond isotope shift of 0.