Exact statistical mechanical treatment of benzene adsorption in a zeolite twin-pore one-dimensional lattice model

Exact statistical mechanical one-dimensi

Exact statistical mechanical one-dimensional lattice model of alkane binary mixture adsorption in zeolites and comparision with Monte-Carlo simulations

✍ Lawrence J. Dunne; George Manos; Zhimei Du 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 199 KB

Adsorption isotherms obtained by Monte-Carlo simulation for ethane-methane mixtures in the zeolite silicalite show a highly unusual structure with a shoulder at low coverage and adsorption preference reversal at high pressures whose interpretation is uncertain. To understand this behaviour an exact