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Exact quantum calculations of the kinetic isotope effect: Cross sections and rate constants for the F+HD reaction and role of tunneling

✍ Scribed by De Fazio, Dario; Aquilanti, Vincenzo; Cavalli, Simonetta; Aguilar, Antonio; Lucas, Josep M.


Book ID
121262491
Publisher
American Institute of Physics
Year
2006
Tongue
English
Weight
758 KB
Volume
125
Category
Article
ISSN
0021-9606

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Using the laser photolysis vacuum-UV laser-induced fluorescence 'pump-and-probe' technique, Doppler profiles of H and D atoms from the reaction O(1D) + HD were measured under single-collision conditions, O(aD) atoms were generated by laser photolysis of N20 at 193 nm. With a calibration method using