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Exact Conditions in Finite-Temperature Density-Functional Theory

✍ Scribed by Pittalis, S.; Proetto, C. R.; Floris, A.; Sanna, A.; Bersier, C.; Burke, K.; Gross, E. K. U.


Book ID
121688859
Publisher
The American Physical Society
Year
2011
Tongue
English
Weight
110 KB
Volume
107
Category
Article
ISSN
0031-9007

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Asymptotic exactness of finite temperatu
✍ H Narnhofer; W Thirring πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 528 KB

By using entropy inequalities with coherent states we prove that for atoms and molecules the partition function of Thomas-Fermi theory becomes exact in the limit Z+ co, in the appropriate scaling. Furthermore the Gibbs state over a suitable algebra converges to a pure state over classical densities