✦ LIBER ✦
Exact calculations of Franck–Condon overlaps and of matrix elements of some potentials by means of the coherent state representation
✍ Scribed by Kiyoshi Nishikawa
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 589 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Franck–Condon overlaps are described as the matrix elements of unitary operators related to the spatial displacement and the frequency shift. They are calculated exactly by means of the coherent state representation. Furthermore, the generalized matrix elements of x^j^, e^−α__x__^, and e^−β__x__^~2~ between two states with different equilibrium coordinates and frequency are evaluated in the same way.