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Exact calculation methods for systems of interlinked columns. Part I: Separation of binary heterogeneous azeotropes

✍ Scribed by Hsien Hsu; J. W. Tierney


Publisher
American Institute of Chemical Engineers
Year
1981
Tongue
English
Weight
711 KB
Volume
27
Category
Article
ISSN
0001-1541

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✦ Synopsis


Abstract

A mathematical model and iterative correction algorithm are described for the exact solution of separation systems which contain interlinked columns in which some stages have two liquid phases and others have a vapor and liquid phase. The correction algorithm is based on Newton's method and provides for simultaneous correction of all iteration variables. The derivatives are calculated analytically from the model equations. The separation of a binary mixture which forms a heterogeneous azeotrope is analyzed. Modifications to the correction algorithm which provide for fixed condenser temperature and fixed product flows are described. The separation of butanol and water is used to illustrate the method.