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Exact Analytical Expressions for the Potential of Electrical Double Layer Interactions for a Sphere−Plate System

✍ Scribed by Lin, Shihong; Wiesner, Mark R.


Book ID
126193388
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
730 KB
Volume
26
Category
Article
ISSN
0743-7463

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Approximate analytical expressions for the electrical potential distribution, surface excess of co-ion, and double-layer free energy and entropy for both cylindrical and spherical surfaces are derived. The present analysis extends previous results in that asymmetric electrolytes are considered. The