Evolution of zirconia coating layer on rutile TiO2 surface and the pigmentary property
β Scribed by Yunsheng Zhang; Hengbo Yin; Aili Wang; Chun Liu; Longbao Yu; Tingshun Jiang; Ying Hang
- Book ID
- 108191752
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 850 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0022-3697
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## Abstract We carried out a theoretical study of the rutile TiO~2~(110) surface using ab initio techniques. We investigate the effects of both surface and subsurface defects. These defects consist of a missing oxygen atom in the crystalline structure, the oxygen vacancy. We show that the defect fo
From calculations of the electrostatic potential at the most densely packed rutile (110) and anatase (001) crystal faces. greater reducibility of the coordinatively unsaturated Ti4' \_ Ions at the rutile surface than at the anatase surface is predicted. Consequently, the intrinsic hewis acidity of c