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Evolution of Self-Assembled Structures of Polymer-Terminated Gold Nanorods in Selective Solvents

โœ Scribed by Daniele Fava; Zhihong Nie; Mitchell A. Winnik; Eugenia Kumacheva


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
376 KB
Volume
20
Category
Article
ISSN
0935-9648

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Reaction of the ligand NN'-bis(pyridin-3-yl)-1,3-benzenedicarboxamide (1) with the diphosphanedigold(I) complex [(mu-PP)(AuO2CCF3)2] occurred by displacement of the trifluoroacetate ligands by the pyridyl groups of 1, and crystallization gave the macrocyclic complex [Au2(mu-PP)(mu-1)](CF3CO2)2 (2b),